A 24-Gd nanocapsule with a large magnetocaloric effect.

Chemical communications (Cambridge, England)

PubMedID: 23133829

Chang LX, Xiong G, Wang L, Cheng P, Zhao B. A 24-Gd nanocapsule with a large magnetocaloric effect. Chem Commun (Camb). 2013;49(11):1055-7.
Two 24-nuclear lanthanide clusters, and were obtained and structurally characterized. Magnetic investigations reveal that exhibits the largest entropy change (-?S(m)) of 46.12 J kg(-1) K(-1) for ?H = 7 T in all reported molecular clusters, and single-molecule magnet behaviour is observed in .